Synthesis of acetylenic alcohols with calcium carbide as the acetylene source

文献信息

发布日期 2013-08-14
DOI 10.1039/C3GC41269E
影响因子 10.182
作者

Yin Ngai Sum, Dingyi Yu, Yugen Zhang


查看原文

摘要

Propargyl alcohols containing a terminal alkyne group are highly important and versatile intermediates. Here, we report the synthesis of these compounds from an inexpensive and renewable resource, calcium carbide (CaC2). No metal catalysts are required in this new protocol and the reactions take place under very mild conditions.

相关文献

Thermophysical properties of glyceline–water mixtures investigated by molecular modelling

Jörg Baz, Christoph Held, Jürgen Pleiss, Niels Hansen

2019-02-25 Paper

DOI: 10.1039/C9CP00036D

Back cover

Cover

DOI: 10.1039/C9CP90087J

Luminescence spectroscopy of oxazine dye cations isolated in vacuo

Christina Kjær, Steen Brøndsted Nielsen

2019-02-04 Paper

DOI: 10.1039/C8CP07340F

Cation influence on heterocyclic ammonium ionic liquids: a molecular dynamics study

Promit Ray, Barbara Kirchner

2019-02-01 Paper

DOI: 10.1039/C8CP07683A

In-plane thermal transport in black phosphorene/graphene layered heterostructures: a molecular dynamics study

Ting Liang, Ping Zhang, Peng Yuan, Siping Zhai

2018-08-06 Paper

DOI: 10.1039/C8CP02831A

Analysis of the interfacial characteristics of BiVO4/metal oxide heterostructures and its implication on their junction properties

Sebastián Murcia-López, Andreas Klein, Roel van de Krol, Teresa Andreu, Joan Ramón Morante, Thierry Toupance, Wolfram Jaegermann

2019-01-29 Paper

DOI: 10.1039/C8CP07483F

Time-resolved IR spectroscopy reveals mechanistic details of ion transport in the sodium pump Krokinobacter eikastus rhodopsin 2

Marvin Asido, Peter Eberhardt, Clara Nassrin Kriebel, Markus Braun, Clemens Glaubitz, Josef Wachtveitl

2019-02-01 Paper

DOI: 10.1039/C8CP07418F

Globule–stretch transition of a self-attracting chain in the repulsive active particle bath

Yi-qi Xia, Wen-de Tian

2019-01-24 Paper

DOI: 10.1039/C8CP05976D

Tannic acid capped gold nanoparticles: capping agent chemistry controls the redox activity

Alex L. Suherman, Giorgia Zampardi, Hatem M. A. Amin, Neil P. Young, Richard G. Compton

2019-02-04 Paper

DOI: 10.1039/C9CP00056A

您可能还喜欢

化合物问答

6-氯-2H-1,4-苯并噁嗪-3(4H)-酮(CAS号:7652-29-1)应用于哪些行业?

6-氯-2H-1,4-苯并噁嗪-3(4H)-酮主要应用于医药、农药和聚合物等领域。在医药领域,该化合物可用于合成抗菌药物;在农药领域,可用作杀虫剂的中间体;在聚...

7652-29-16-Chloro-2H-1,4-benz...
化合物问答

活性氧化铝(CAS号:1302-74-5)应用于哪些行业?

活性氧化铝广泛应用于医药、聚合物、传感器、半导体和催化等领域。在医药行业,活性氧化铝用作吸附剂和干燥剂,有助于去除杂质和水分。在聚合物行业,它用作增白剂和抗结块...

1302-74-5aluminum;trihydrate
化合物问答

什么是硅胶(CAS号:112926-00-8)?

硅胶(Silica gel, pptd.,cryst.-free)是一种无定形、多孔的硅酸盐材料,主要成分为二氧化硅(SiO₂)。其结构由硅氧四面体构成,通过酸...

112926-00-8Silica gel, pptd.,cr...
化合物问答

二乙基甲基一氢硅烷(CAS号:760-32-7)的主要用途是什么?

二乙基甲基一氢硅烷主要用于有机合成、表面处理以及作为溶剂。它还被用作合成其他硅烷化合物的原料,以及在涂料、粘合剂和密封剂中的应用。

760-32-7Diethyl(methyl)silan...
化合物问答

在合成中是否有N-花生四烯酰基甘氨酸(CAS号:179113-91-8)的替代品?

在合成过程中,可以考虑使用类似结构的化合物作为替代品,例如N-亚油酰基甘氨酸或N-花生二烯酰基甘氨酸。这些替代品在结构上有类似的双键位置,但可能具有不同的物理化...

179113-91-8Glycine, N-[(5Z,8Z,1...
化合物问答

在合成中是否有1-(4-甲氧基苯基)丙烷-1,2-二酮(CAS号:10557-27-4)的替代品?

在合成过程中,可以考虑使用类似结构的化合物作为替代品,例如1-(3-甲氧基苯基)丙烷-1,2-二酮或1-(4-羟基苯基)丙烷-1,2-二酮。这些替代品具有相似的...

10557-27-41-(4-Methoxyphenyl)p...
化合物问答

N-(4-氨基-1-苄基-3-羟基-5-苯基戊基)-3-甲基-2-(2-氧代四氢嘧啶-1-基)-丁酰胺 5-氧代吡咯烷-2-甲酸(CAS号:192726-06-0)通常如何合成?

该化合物通常通过一系列复杂的有机合成步骤获得。首先,通过芳香族化合物的羟基化反应获得羟基化产物,然后通过酰化反应形成酰胺中间体,最后通过环化反应得到目标产物。常...

192726-06-05-Oxo-L-proline - (2...
化合物问答

(S)-2-氨基-3-喹啉-2-丙酸(CAS号:161513-46-8)的市场或研究趋势如何?

该化合物作为生物活性化合物,尤其是在药物化学领域表现出色。近年来,随着对新型抗炎、抗病毒和抗癌药物的研究增加,其市场和研究趋势持续增长。此外,其在神经科学领域的...

161513-46-8(S)-2-Amino-3-quinol...
化合物问答

核黄素磷酸钠(CAS号:130-40-5)安全吗?

核黄素磷酸钠在常规使用条件下安全,但高剂量可能引起刺激性反应。操作时需佩戴防护手套和护目镜,避免吸入粉尘。若接触皮肤或眼睛,应立即用大量清水冲洗。急救时需根据接...

130-40-5Sodium 1-deoxy-1-(7,...
化合物问答

盐酸丙胺卡因杂质A(EP) 标准品(CAS号:19281-31-3)通常如何合成?

盐酸丙胺卡因杂质A(EP) 标准品可通过重氮化反应和随后的酰胺化反应合成。首先,利用氯化反应将苯环上的氢原子转化为氯原子,然后通过芳香族重氮化反应引入氨基,最后...

19281-31-32-Chloro-N-(2-methyl...

来源期刊

Green Chemistry

Green Chemistry
CiteScore: 16.1
自引率: 7.5%
年发文量: 944

Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.

推荐供应商

免责声明
本页面提供的学术期刊信息仅供参考和研究使用。我们与任何期刊出版商均无关联,也不处理投稿事宜。如有投稿相关咨询,请直接联系相关期刊出版商。
如发现页面信息有误,请发送邮件至 support@chemtradehub.com 联系我们。我们将及时核实并处理您的问题。