A self-healing supramolecular polymer gel with stimuli-responsiveness constructed by crown ether based molecular recognition

文献信息

发布日期 2013-03-12

DOI 10.1039/C3PY00283G

影响因子 5.582

作者

Xuzhou Yan, Donghua Xu, Jianzhuang Chen, Mingming Zhang, Bingjie Hu, Yihua Yu, Feihe Huang

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摘要

A cross-linked supramolecular polymer network gel was prepared by orthogonal self-assembly of two homoditopic monomers and a metallic cross-linker. The gel is transparent and free-standing, which not only shows an interesting gel–sol transition in response to quadruple-stimuli, but also exhibits self-healing properties, as can be seen by the naked eye and as evidenced by rheological characterization. These unique features are all due to the dynamically reversible host–guest complexation and good mechanical properties of the cross-linked polymer network. Therefore, these fascinating properties make this supramolecular gel an unprecedentedly intelligent material.

期刊推荐

Annual Review of Materials Research

Phytochemistry Reviews

Catalysis Communications

Nature Materials

Medicinal Chemistry

Crystal Growth & Design

Nature Methods

Dalton Transactions

Physics of Life Reviews

Mini-Reviews in Organic Chemistry

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

A self-healing supramolecular polymer gel with stimuli-responsiveness constructed by crown ether based molecular recognition

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来源期刊

Polymer Chemistry

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