Thiophene based hyperbranched polymers with tunable branching using direct arylation methods

文献信息

发布日期 2013-04-15

DOI 10.1039/C3PY00412K

影响因子 5.582

作者

Forrest E. Michael

查看原文

摘要

An efficient one-pot synthesis of branched poly(3-alkylthiophene)s (b-P3ATs) is achieved via a dehydrohalogenative polycondensation reaction. The structures of the b-P3ATs are assigned based on 1H NMR spectra by comparing them to a model dendritic polymer and oligo(3-hexylthiophene-2,4-diyl). The palladium-catalyzed dehydrohalogenative polycondensation of 2-bromo-3-alkylthiophenes was found to provide P3AT with tunable degree of branching (DB = 0–0.42) and high molecular weights. Viscosity measurements of the different b-P3ATs indicate that they display a more globular morphology compared to regiorandom P3AT and regioregular P3AT in solution, thereby confirming the branched structure.

期刊推荐

Catalysis Today

Composite Interfaces

Advanced Materials

Journal of Computer-Aided Molecular Design

Main Group Metal Chemistry

Construction and Building Materials

Advanced Powder Technology

Heterocyclic Communications

Cement and Concrete Composites

Diamond and Related Materials

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Thiophene based hyperbranched polymers with tunable branching using direct arylation methods

文献信息

期刊推荐

相关文献

l-Proline catalyzed asymmetric transfer aldol reaction between diacetone alcohol and aldehydes

A thermally stable nanoporous nickel 5-sulfoisophthalate; crystal structure and adsorption properties

Stereoelective polymerization of d,l-lactide using N-heterocyclic carbene based compounds

First lanthanide dipolar complexes for second-order nonlinear optics

Isolation and characterisation of the mixed-metal alkyl amide [(TMEDA)Na(μ-Bu)(μ-TMP)Mg(TMP)], an unexpected chelate-trapped intermediate in the formation of inverse crowns

Highly efficient epoxidation method of olefins with hydrogen peroxide as terminal oxidant, bicarbonate as a co-catalyst and oxodiperoxo molybdenum(vi) complex as catalyst

Ionic hydrogenation of C-20, 22-ketene dithioacetal: stereoselective synthesis of steroidal C (20R) aldehydes

The mechanism of polyleucine catalysed asymmetric epoxidation

The first samarium(ii)-mediated aryl radical cyclisation onto an aromatic ring

Aminooxazolinate; a chiral amidinate analogue

您可能还喜欢

如何处理含有3-氯苯甲酰肼(CAS号：1673-47-8)的废料？

(2E)-N-(2-氨基-4-氟苯基)-3-[1-(3-苯基-2-丙烯-1-基)-1H-吡唑-4-基]-2-丙烯酰胺(CAS号：1396841-57-8)应用于哪些行业？

什么是对-N,N-二甲氨基苯甲酸乙酯(CAS号：10287-53-3)？

3,6-二溴-9-(4-甲基苯基)-9H-咔唑(CAS号：357437-74-2)的物理化学性质是什么？

在合成中是否有FMOC-(2R,4S)-PRO(4-F)-OH(CAS号：913820-87-8)的替代品？

2-苄基八氢环戊并[c]吡咯-4-胺(CAS号：186201-60-5)的主要用途是什么？

奥氮平N乙酰基杂质(CAS号：935272-10-9)的市场或研究趋势如何？

处理Chloropropylate(CAS号：5836-10-2)时应注意哪些实验室安全事项？

在合成中是否有4-氢氯化氨基安替比林(CAS号：22198-72-7)的替代品？

如何处理含有3-脱氧-D-葡糖酮醛(CAS号：4084-27-9)的废料？

来源期刊

Polymer Chemistry

推荐化合物

Adipic Acid

Sodium Benzoate

Potassium iodide

Benzoic Acid

1-Methyl-2-pyrrolidinone

推荐供应商