ZnO nanorods on reduced graphene sheets with excellent field emission, gas sensor and photocatalytic properties

文献信息

发布日期 2013-05-16
DOI 10.1039/C3TA11490B
影响因子 12.732
作者

Rujia Zou, Guanjie He, Kaibing Xu, Qian Liu, Zhenyu Zhang, Junqing Hu


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摘要

In the flexible devices' fabrication, highly ordered nanoscale texturing such as semiconductor metal oxide nanorod arrays on the flexible substrates is critical for optimal performance. Herein, a simple and general hydrothermal route has been developed to result in a large-scale growth of ZnO nanorod arrays on double sides of the flexible reduced graphene sheets (rGss) forming sandwichlike heterostructures of ZnO/G/ZnO, and on a single side of the flexible rGss forming two-layered heterostructures of ZnO/G. The diameter and density of the ZnO nanorods grown on the rGss can be easily tuned as required by varying the seed-solution concentration. Due to the outstanding mechanical and electrical properties of the rGss, two-layered ZnO/G heterostructures were demonstrated to possess excellent field emission properties (turn-on field as low as 2.1 V μm−1, the emitting current ∼470 μA cm−2 at 3 V μm−1) and gas sensing (three times the ZnO nanorods); the sandwichlike ZnO/G/ZnO heterostructures have much higher photocatalytic activity under UV irradiation than those of ZnO nanorods and ZnO/G heterostructures, suggesting a promising candidate for photocatalytic decontamination. This would open up possibilities for the extensive study of the physical and chemical properties from these most promising nanostructures and extend their practical applications.

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来源期刊

Journal of Materials Chemistry A

Journal of Materials Chemistry A
CiteScore: 19.5
自引率: 4.7%
年发文量: 2211

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment

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