Accurate characterization of single track-etched, conical nanopores

Single track-etched conical nanopores in polymer foils have attracted considerable attention in recent years due to their potential applications in biosensing, nanofluidics, information processing, and other fields. The performance of a nanopore critically depends on the size and shape of its narrowest, nanometer-sized region. In this paper, we reconstructed the profiles of both doubly-conical and conical pores, using an algorithm based on conductometric measurements performed in the course of etching, coupled with SEM data. We showed that pore constriction deviates from the conical shape, and the deviation depends on the energy loss of the particle that produced the track. Funnel-like profiles of tracks of four ions with different atomic numbers were derived from experimental data. The simulations, using a Poisson–Nernst–Planck model, demonstrated that the ion current rectification properties of the funnel-shaped asymmetrical pores significantly differ from those of conical ones if the tip radius of the pore is smaller than 10 nm. Upon subjecting to further etching, the pores gradually approach the “ideal” conical geometry, and the ion transport properties of these two pore configurations become almost indistinguishable.