A new working mode for molecular springs: water intrusion induced by cooling and associated isobaric heat capacity change of a {ZIF-8 + water} system
文献信息
V. Eroshenko
Hydrophobic microporous metal–organic framework ZIF-8 combined with water forms a molecular spring (MS), which by the forced intrusion of water into the pores and its spontaneous extrusion can store and restore large amounts of mechanical and thermal energy. Using scanning transitiometry technique, we demonstrate that the simultaneous effect of temperature and pressure on the porosity of ZIF-8 leads to a non-standard temperature dependence of intrusion and extrusion pressures of MS, which allows to provoke water intrusion into the hydrophobic pores of ZIF-8 by decreasing the temperature of the system under constant pressure. A remarkably strong effect of intrusion on the isobaric heat-capacity of {ZIF-8 + water} MS is discovered.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












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