Calibration of the basic strength of the nitrogen groups on the nanostructured carbon materials
文献信息
Bo Li, XiaoYing Sun, Dangsheng Su
The basicity of the graphitic, pyridine, and pyrrole nitrogen groups on the graphene and single-walled carbon nanotubes is evaluated and compared in terms of both Brønsted base and Lewis base. It turns out that the pyridine group is the most strong basic site, while the graphitic nitrogen does not bring any improvements over the undoped one.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












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