Highly efficient visible-light-driven photoelectro-catalytic selective aerobic oxidation of biomass alcohols to aldehydes
文献信息
Yajun Zhang, Guohua Zhao, Yanan Zhang, Xiaofeng Huang
A green and highly efficient visible-light-driven synergistic photoelectrochemical (PEC) catalysis system was systematically demonstrated for selective oxidation of biomass alcohols to the corresponding aldehydes in an O2 atmosphere under the mild conditions by employing the Au/CeO2–TiO2 NTs as photocathodes. Results showed that the conversion of benzyl alcohols was as high as 98% and the selectivity of benzaldehyde was >99% at the bias potential of −0.8 V under the visible light irradiation for 8 h. The superior performance could be attributed to the synergistic PEC process combining both the advantages of photocatalytic and electrocatalytic activity. Furthermore, the research elucidated that the PEC activity and the conversion rate of benzyl alcohol could be effectively promoted by adjusting the potential. Interestingly, the incorporation of CeO2 nanoparticles (NPs) into the inner wall of TiO2 NTs can remarkably enhance the selectivity of the PEC oxidation reaction towards a specific direction. Additionally, the rationally designed and fabricated Au/CeO2–TiO2 NT photocathode was in favour of separating electrons and holes. A probable mechanism for the PEC selective aerobic oxidation process was proposed and discussed.
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Green Chemistry

Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.












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