Bimetallic nickel and cobalt complexes as high-performance catalysts for copolymerization of carbon dioxide with cyclohexene oxide
文献信息
Hui-Ju Chuang, Chen-Yu Li, Bao-Tsan Ko, Chia-Her Lin
New bimetallic nickel, cobalt and zinc complexes bearing a bis(benzotriazole iminophenolate) ligand and ancillary acetate groups were developed for CO2/epoxide copolymerization. Ni and Co complexes are active catalysts for the copolymerization of cyclohexene oxide (CHO) and CO2 without co-catalysts. Particularly, well-defined di-Ni 1 was found to effectively copolymerize CHO with CO2, giving copolymers with a high molecular weight and a high carbonate linkage content. This is the first example of a dinuclear nickel acetate complex that is efficient for CO2/CHO copolymerization as well as for the formation of highly alternative poly(cyclohexene carbonate) in a controllable manner.
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Chemistry Education Research and Practice

Chemical Communications

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Russian Chemical Bulletin

Current Opinion in Colloid & Interface Science

Drug Discovery Today

Organic Process Research & Development

Russian Journal of Bioorganic Chemistry

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Journal of Saudi Chemical Society
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Polymer Chemistry

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