Metal Ni-loaded g-C3N4 for enhanced photocatalytic H2 evolution activity: the change in surface band bending

文献信息

发布日期 2015-10-14
DOI 10.1039/C5CP05158D
影响因子 3.676
作者

Lingling Bi, Dandan Xu, Lijing Zhang, Yanhong Lin, Tengfeng Xie


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摘要

A series of Ni@g-C3N4 composites were synthesized by a simple solvent thermal method using melamine and acetylacetone nickel as precursors. The results of X-ray diffraction, transmission electron microscopy and high resolution transmission electron microscopy indicate that Ni was successfully loaded on g-C3N4. And the Ni loaded greatly enhances the photocatalytic H2 evolution activity of g-C3N4 compared to the pure g-C3N4. In order to study the role of Ni, the surface photovoltage, the surface photocurrent and photoluminescence measurements were used to investigate the photogenerated charge properties of g-C3N4. What is more, Mott–Schottky plots and work function measurements confirmed the surface band bending change of g-C3N4 contacting with Ni. Those results demonstrate that Ni coating deepens surface band bending of g-C3N4, resulting in higher separation efficiency of photogenerated charge carriers, which is contributed to the enhanced photocatalytic H2 evolution activity.

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来源期刊

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
自引率: 10.3%
年发文量: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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