ADMET and TAD chemistry: a sustainable alliance

文献信息

发布日期 2016-08-16

DOI 10.1039/C6PY01144F

影响因子 5.582

作者

L. Vlaminck, K. De Bruycker, O. Türünç, F. E. Du Prez

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摘要

A versatile, additive-free post-polymerisation functionalisation method for acyclic diene metathesis (ADMET) derived polymers, utilising 1,2,4-triazoline-3,5-dione (TAD) chemistry, is reported. Several diene monomers have been synthesised starting from 10-undecenoic acid derivatives and subsequently polymerised via ADMET polymerisation reaction. Post-polymerisation functionalisation of the poly-unsaturated macromolecules with several substituted TAD compounds was shown to achieve full conversions within 6 hours. Also, the functionalised polymers could be chemically crosslinked with a bivalent triazolinedione crosslinker. The glass transition temperature of the resulting materials could be tuned by varying the degree of functionalisation, the polymer backbone, the TAD substituent and the crosslinking density.

期刊推荐

Synthetic Communications

Drug and Chemical Toxicology

Bulletin of Materials Science

Annual Review of Public Health

Journal of Dispersion Science and Technology

Studies in Conservation

Tetrahedron Letters

Journal of Natural Products

Applied Surface Science

Tetrahedron

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

ADMET and TAD chemistry: a sustainable alliance

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Polymer Chemistry

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