Circularly polarized luminescence based chirality transfer of the chiral BINOL moiety via rigid π-conjugation chain backbone structures

文献信息

发布日期 2017-01-30

DOI 10.1039/C6PY02218A

影响因子 5.582

作者

Fandian Meng, Yunzhi Li, Wenjie Zhang, Shuhua Li, Yiwu Quan, Yixiang Cheng

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摘要

Three kinds of chiral BINOL-based polymers could be synthesized by polymerization in a Pd-catalyzed cross-coupling reaction. The resulting chiral polymers can exhibit strong mirror image Cotton effects. Interestingly, only P2 and P3 can emit circularly polarized luminescence (CPL) signals, which can be attributed to the chirality transfer of the BINOL moiety via the rigid π-conjugation chain backbone structure system. This work can develop a new strategy for the design of novel CPL materials.

期刊推荐

Heteroatom Chemistry

Journal of the Indian Institute of Science

Critical Reviews in Solid State and Materials Sciences

Electroanalysis

Polycyclic Aromatic Compounds

Topics in Catalysis

Acta Metallurgica Sinica-English Letters

NDT & E International

Bioorganic & Medicinal Chemistry

Biocatalysis and Biotransformation

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Circularly polarized luminescence based chirality transfer of the chiral BINOL moiety via rigid π-conjugation chain backbone structures

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