Circularly polarized luminescence based chirality transfer of the chiral BINOL moiety via rigid π-conjugation chain backbone structures
文献信息
发布日期
2017-01-30
DOI
10.1039/C6PY02218A
影响因子
5.582
作者
Fandian Meng, Yunzhi Li, Wenjie Zhang, Shuhua Li, Yiwu Quan, Yixiang Cheng
查看原文
摘要
Three kinds of chiral BINOL-based polymers could be synthesized by polymerization in a Pd-catalyzed cross-coupling reaction. The resulting chiral polymers can exhibit strong mirror image Cotton effects. Interestingly, only P2 and P3 can emit circularly polarized luminescence (CPL) signals, which can be attributed to the chirality transfer of the BINOL moiety via the rigid π-conjugation chain backbone structure system. This work can develop a new strategy for the design of novel CPL materials.
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来源期刊
Polymer Chemistry
CiteScore:
8.6
自引率:
7.3%
年发文量:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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