Grafting challenging monomers from proteins using aqueous ICAR ATRP under bio-relevant conditions

文献信息

发布日期 2017-06-13

DOI 10.1039/C7PY00669A

影响因子 5.582

作者

Theresa Ramelot, Dominik Konkolewicz, Scott Graner

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摘要

Aqueous initiators for continuous activator regeneration atom transfer radical polymerization (ICAR ATRP) was applied to graft well defined acrylamide, N,N-dimethylacrylamide and N-vinylimidazole homo and block copolymers from a model protein initiator (bovine serum albumin (BSA)) under bio-relevant conditions. Using N-vinylimidazole as a ligand catalytic biohybrid nanoparticles were prepared by loading palladium into a block copolymer of poly(N-vinylimidazole)-b-poly(oligo(ethylene oxide) acrylate) grafted from BSA. The protein–polymer biohybrid catalyst successfully catalyzes Suzuki–Miyaura couplings in aqueous media under aerobic conditions.

期刊推荐

Experimental Techniques

Organometallics

Composites Science and Technology

Journal of the Royal Society of New Zealand

Natural Product Reports

Ferroelectrics Letters Section

Composite Structures

Fire and Materials

Geotextiles and Geomembranes

Bulletin of the Korean Chemical Society

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Grafting challenging monomers from proteins using aqueous ICAR ATRP under bio-relevant conditions

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来源期刊

Polymer Chemistry

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