Methodology and applications of the hexadehydro-Diels–Alder (HDDA) reaction

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发布日期 2017-03-20

DOI 10.1039/C7QO00071E

影响因子 5.281

作者

Todd B. Marder

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摘要

The hexadehydro-Diels–Alder (HDDA) reaction between an alkyne and a 1,3-diyne has recently become a rapidly growing area in the field of aryne chemistry. Both concerted and stepwise mechanisms for HDDA are energetically and geometrically feasible. The formation of a reactive benzyne intermediate under thermal conditions has been coupled with a wide variety of intra- and intermolecular trapping reactions to access highly functionalised aromatic compounds. With this in mind, reagents can be tailored to generate compounds for desired applications such as the synthesis of bioactive molecules or optoelectronic materials. This review presents a comprehensive overview of the HDDA reaction to date.

期刊推荐

Science

Journal of Physics and Chemistry of Solids

Science Progress

Proceedings of the National Academy of Sciences of the United States of America

Journal of Catalysis

Nature

Pure and Applied Chemistry

Kinetics and Catalysis

Journal of Medicinal Chemistry

Fibre Chemistry

来源期刊

Organic Chemistry Frontiers

CiteScore: 7.8

自引率: 8.7%

年发文量: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Methodology and applications of the hexadehydro-Diels–Alder (HDDA) reaction

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