Exploring the hidden potential of a benzothiazole-based Schiff-base exhibiting AIE and ESIPT and its activity in pH sensing, intracellular imaging and ultrasensitive & selective detection of aluminium (Al3+)

文献信息

发布日期 2018-06-11

DOI 10.1039/C8AN00349A

影响因子 4.616

作者

Vishal Kachwal, I. S. Vamsi Krishna, Leena Fageria, Jagrity Chaudhary, Ram Kinkar Roy, Rajdeep Chowdhury, Inamur Rahaman Laskar

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摘要

In this article, we tried to redefine the unexplored potential of a benzothiazole type of Schiff-base (OM), which was identified as an AIE-active molecule that exhibits excited-state intramolecular proton transfer (ESIPT). Interestingly, this compound shows ultra-sensitivity and selectivity in the detection of Al(III) (12 pM; 456 ppt). The OM was capable of pH sensing and was also tested for internalization in cancerous cells for intracellular imaging. Computational modeling was performed and the results were in good agreement with the experimental UV-Vis spectrum and the energy gap obtained in basic and acidic media.

期刊推荐

Nature

Journal of Catalysis

Helvetica Chimica Acta

Journal of Heterocyclic Chemistry

Proceedings of the National Academy of Sciences of the United States of America

Journal of Medicinal Chemistry

Pure and Applied Chemistry

Organic Preparations and Procedures International

Israel Journal of Chemistry

Journal of Physics and Chemistry of Solids

来源期刊

Analyst

CiteScore: 7.8

自引率: 5.6%

年发文量: 653

Analyst publishes analytical and bioanalytical research that reports premier fundamental discoveries and inventions, and the applications of those discoveries, unconfined by traditional discipline barriers.

Exploring the hidden potential of a benzothiazole-based Schiff-base exhibiting AIE and ESIPT and its activity in pH sensing, intracellular imaging and ultrasensitive & selective detection of aluminium (Al3+)

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