Regioselective nitration of anilines with Fe(NO3)3·9H2O as a promoter and a nitro source
文献信息
Yang Gao, Yuanyou Mao, Biwei Zhang, Yingying Zhan, Yanping Huo
An efficient Fe(NO3)3·9H2O promoted ortho-nitration reaction of aniline derivatives has been developed. This reaction may go through a nitrogen dioxide radical (NO2˙) intermediate, which is generated by the thermal decomposition of iron(III) nitrate. The practicality of the present method using nontoxic and inexpensive iron reagents has been shown by the broad substrate scope and applications.
期刊推荐

Electroanalysis

Critical Reviews in Solid State and Materials Sciences

Chinese Journal of Chemistry

Bioorganic & Medicinal Chemistry Letters

Heteroatom Chemistry

Colloid Journal

Journal of Asian Natural Products Research

Journal of the Indian Institute of Science

Herald of the Russian Academy of Sciences

Bioorganic & Medicinal Chemistry
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Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.
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