Modular synthesis of (E)-cinnamaldehydes directly from allylarenes via a metal-free DDQ-mediated oxidative process

文献信息

发布日期 2018-07-09

DOI 10.1039/C8OB01469H

影响因子 3.876

作者

Ting-Ting Xu, Tao-Shan Jiang, Xiao-Lan Han, Yuan-Hong Xu, Jin-Ping Qiao

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摘要

An efficient synthesis of (E)-cinnamaldehydes by a metal-free DDQ-mediated oxidative transformation of allylarenes was developed. The protocol provides a practical method to prepare diverse (E)-cinnamaldehydes with broad functional group tolerance in good to excellent yields, including easy access to natural products randainal and geranyloxy sinapyl aldehyde from plant extracts. Finally, the mechanism of a single-electron transfer process was proposed.

期刊推荐

Journal of Organometallic Chemistry

Journal of Physics and Chemistry of Solids

Journal of Catalysis

Russian Chemical Reviews

Journal of Heterocyclic Chemistry

Proceedings of the National Academy of Sciences of the United States of America

Kinetics and Catalysis

Israel Journal of Chemistry

Science Progress

Organic Preparations and Procedures International

来源期刊

Organic & Biomolecular Chemistry

CiteScore: 3.4

自引率: 10.3%

年发文量: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

Modular synthesis of (E)-cinnamaldehydes directly from allylarenes via a metal-free DDQ-mediated oxidative process

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Organic & Biomolecular Chemistry

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