The nanoscopic principles of capacitive ion sensing interfaces
文献信息
Paulo R. Bueno, Robert Hein, Adriano Santos, Jason J. Davis
Herein we discuss the operational principles of molecular interfaces that specifically recruit ions from an electrolyte solution and report this in a reagentless capacitive manner. At low ionic occupancy the response of the interface obeys a Debye-type phenomenon akin to classic “image charge” effects. At higher levels of occupancy, the response follows Thomas–Fermi screening and, significantly, is dependent on the electronic structure of the mesoscopic ion–receptor host–guest ensemble.
相关文献
Long-term-stability continuous flow CO2 reduction electrolysers with high current efficiency
Yueyuan Gu, Jucai Wei, Jindong Li, Xu Wu
DOI: 10.1039/D0SE01707H
Techno-economic analysis of a sustainable process for converting CO2 and H2O to feedstock for fuels and chemicals
Aniruddha P. Kulkarni, Tomy Hos, Miron V. Landau, Daniel Fini, Sarbjit Giddey, Moti Herskowitz
DOI: 10.1039/D0SE01125H
Selective electrochemical reduction of CO2 to formic acid in a gas phase reactor with by-product recirculation
Barbara Thijs, Jan Rongé, Johan A. Martens
DOI: 10.1039/D1SE00218J
Ferrocene-based porous organic polymer derived N-doped porous carbon/Fe3C nanocrystal hybrids towards high-efficiency ORR for Zn–air batteries
Xia Liu, Xiaoming Liang, Han Lou, Huiru Wang, Hui Li, Shujuan Zhang, Shourong Zhu, Weina Han
DOI: 10.1039/D0SE01692F
Enhanced OER performance of composite Co–Fe-based MOF catalysts via a one-pot ultrasonic-assisted synthetic approach
Fen Li, Jinxia Li, Lihui Zhou, Sheng Dai
DOI: 10.1039/D0SE01750G
Crystal size-controlled growth of bismuth vanadate for highly efficient solar water oxidation
Qi Qin, Qian Cai, Wei Liu
DOI: 10.1039/D0SE01642J
Screening adsorbent–water adsorption heat pumps based on an experimental water adsorption isotherm database
Peyman Z. Moghadam
DOI: 10.1039/D0SE01824D
Fine-tuning the water oxidation performance of hierarchical Co3O4 nanostructures prepared from different cobalt precursors
Avani Chunduri, Nainesh Patel, Dattatray S. Dhawale, Ajayan Vinu, Hind Aljohani
DOI: 10.1039/D0SE01711F
Impacts of metal oxide additives on the capacity and stability of calcium oxide based materials for the reactive sorption of CO2
Luke T. Minardi, Faisal H. Alshafei, Zubin K. Mishra, Dante A. Simonetti
DOI: 10.1039/D0SE01638A
Effect of cellulase on the UCST behavior of sulfobetaine zwitterionic surfactants and the cellulase recovery mechanism
Feiyun Li, Feiyang Qin, Cheng Cai, Yuxia Pang, Weifeng Liu, Qiong Li, Xueqing Qiu
DOI: 10.1039/D0SE01158D
您可能还喜欢
甲基双烯双酮(CAS号:5173-46-6)通常如何合成?
甲基双烯双酮可以通过多种途径合成。一种常见的合成方法是通过甲基化和环化反应,先由4-甲基-9-烯-1,3-二酮合成,然后进行环化反应得到目标产物。具体的合成路线...
如何处理含有tert-butyl 3,5-difluorobenzoate(CAS号:467442-11-1)的废料?
处理含有tert-butyl 3,5-difluorobenzoate(CAS号:467442-11-1)的废液时,应首先收集并密封,避免泄漏。随后,建议通过焚...
4-二甲氧基甲基-2-(三氟甲基)嘧啶(CAS号:878760-47-5)通常如何合成?
4-二甲氧基甲基-2-(三氟甲基)嘧啶通常通过三氟甲基化反应合成。首先,将2-氯嘧啶与三氟甲基锂在惰性溶剂中反应,然后将得到的三氟甲基化中间体与二甲氧基甲基化试...
WRW4(CAS号:878557-55-2)的主要用途是什么?
WRW4主要应用于科学研究领域,尤其是在合成化学和有机合成方面。由于其特殊的化学性质,它可能被用于特定的化学反应或合成过程。
什么是6-O-(三异丙基硅基)-D-葡萄烯糖(CAS号:137915-37-8)?
6-O-(三异丙基硅基)-D-葡萄烯糖是一种有机化合物,化学名为1,5-Anhydro-2-deoxy-6-O-(triisopropylsilyl)-D-ar...
N-Benzyl-N,N-dimethyl-2-phenoxyethanaminium(CAS号:7181-73-9)的主要用途是什么?
N-Benzyl-N,N-dimethyl-2-phenoxyethanaminium在有机合成中被用作保护基团,可以用于保护氨基,提高反应的选择性和产率。此外...
什么是3-(Cyclohex-1-en-1-yl)acrylic acid(CAS号:56453-88-4)?
3-(Cyclohex-1-en-1-yl)acrylic acid,简称3-环己烯-1-烯丙酸,是一种含有环己烯基团的丙烯酸衍生物,用于合成其他化合物或作为有...
如何储存(1R)-7-fluoro-1,2,3,4-tetrahydronaphthalen-1-amine(CAS号:1055949-62-6)?
应将(1R)-7-氟-1,2,3,4-四氢萘胺储存于阴凉、干燥、通风良好的地方,远离火源和热源。避免与氧化剂、酸类接触。使用合适的容器,密封保存。
3-甲基苯并呋喃-2-羧酸(CAS号:24673-56-1)的主要用途是什么?
3-甲基苯并呋喃-2-羧酸主要用作合成其他化合物的中间体,如药物合成、有机合成等领域。此外,该化合物在某些领域作为化学试剂或分析试剂使用。
孕烷醇酮(CAS号:128-20-1)适用哪些法规指南?
孕烷醇酮(CAS号:128-20-1)需遵守GHS(全球化学品统一分类和标签制度)的相关分类和标签要求,主要涉及健康危害、环境危害和物理化学危害。此外,还需要遵...
来源期刊
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














