![5-Bromoimidazo[1,2-a]pyridine structure](https://cnstatic.chemtradehub.com/structs/692/69214-09-1-d8e2.webp "5-Bromoimidazo[1,2-a]pyridine structure")
Synthesis, photophysical properties, and self-dimerization studies of 2-λ5-phosphaquinolin-2-ones
文献信息
发布日期
2019-03-25
DOI
10.1039/C9QO00199A
影响因子
5.281
作者
Jeremy P. Bard, Chun-Lin Deng, Hannah C. Richardson, Jacob M. Odulio, Joshua E. Barker, Lev N. Zakharov, Paul H.-Y. Cheong, Darren W. Johnson, Michael M. Haley
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摘要
We have rationally designed and synthesized a library of phosphaquinolinone derivatives containing various electron-donating and -withdrawing groups on two positions of the scaffold. Distinct trends are observed between the substituents on R1 and R2 with both the photophysical properties of the molecules and their dimerization strengths. With withdrawing groups upon the scaffold, dimerization constants surpass 500 M−1 in H2O-saturated CDCl3. Computational studies on the dimeric structures corroborate the experimental findings.
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来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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