An unexpected reaction of aryldiazonium tetrafluoroborates, sodium metabisulfite, and thiourea under photoinduced conditions
文献信息
发布日期
2019-04-11
DOI
10.1039/C9QO00410F
影响因子
5.281
作者
Xiaofang Li, Wenlin Xie, Shengqing Ye
查看原文
摘要
A photoinduced synthesis of S-aryl thiosulfonates through a three-component reaction of aryldiazonium tetrafluoroborates, sodium metabisulfite, and thiourea is achieved. The reaction scope generality with a range of aryldiazonium tetrafluoroborates is demonstrated. In this transformation, a radical coupling pathway is proposed with the insertion of sulfur dioxide in the presence of a photocatalyst under visible light irradiation. The organic sulfur motifs in S-aryl thiosulfonates originate from the convenient, cheap, and easily available thiourea and sodium metabisulfite.
期刊推荐
Bioorganic & Medicinal Chemistry Letters
Bioorganic & Medicinal Chemistry
Herald of the Russian Academy of Sciences
Critical Reviews in Solid State and Materials Sciences
Electroanalysis
Journal of Asian Natural Products Research
Biocatalysis and Biotransformation
Main Group Chemistry
Chinese Journal of Chemistry
Acta Metallurgica Sinica-English Letters
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来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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