A facile synthesis of a novel triptycene-containing A–B monomer: precursor to polymers of intrinsic microporosity

文献信息

发布日期 2011-10-26
DOI 10.1039/C1PY00423A
影响因子 5.582
作者

Bader S. Ghanem


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摘要

A new synthetic approach affords the first example of a triptycene-containing A–B monomer bearing both phenazine activating aromatic o-dichloride and a catecholgroup which can be used for the synthesis of a novel polymer of intrinsic microporosity (PIM) has been developed. The new polymer was characterized by GPC, IR, and 1H NMR, elemental analysis and demonstrated good porosity, thermal stability and solubility in common organic solvents such as chloroform from which a self-supporting and transparent film could be cast.

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来源期刊

Polymer Chemistry

Polymer Chemistry
CiteScore: 8.6
自引率: 7.3%
年发文量: 457

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