Orthogonally arranged tripyrrin–BODIPY conjugates with an “edge to plane” mode
文献信息
发布日期
2019-04-25
DOI
10.1039/C9QO00445A
影响因子
5.281
作者
Chun-Liang Hou, Yuhang Yao, Da Wang, Jing Zhang, Jun-Long Zhang
查看原文
摘要
We designed new molecular conjugates, consisting of two strong fluorophores, tripyrrin and BODIPY moieties. Crystal structures demonstrated that the BODIPY is nearly perpendicular to the tripyrrin plane, directly linked in an orthogonal geometry, in a new “edge to plane” mode with covalently bonded chromophore peripheries. Furthermore, substitutions on BODIPY can modulate the photophysical properties, which can be explained by energy transfer via a FRET mechanism. This not only enriches the repertoire of multichromophoric system but also expands the scope of tripyrrin for constructing molecular functional materials.
期刊推荐
NDT & E International
Main Group Chemistry
Topics in Catalysis
Journal of Asian Natural Products Research
Journal of the Indian Institute of Science
Herald of the Russian Academy of Sciences
Chinese Journal of Chemistry
Critical Reviews in Solid State and Materials Sciences
Bioorganic & Medicinal Chemistry Letters
Polycyclic Aromatic Compounds
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来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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