![2,6-Di(thiophen-2-yl)dithieno[3,2-b:2',3'-d]thiophene structure](https://cnstatic.chemtradehub.com/structs/910/910788-24-8-5b70.webp "2,6-Di(thiophen-2-yl)dithieno[3,2-b:2',3'-d]thiophene structure")
Transition metal-free electrocatalytic halodeborylation of arylboronic acids with metal halides MX (X = I, Br) to synthesize aryl halides
文献信息
发布日期
2020-01-06
DOI
10.1039/C9QO01139K
影响因子
5.281
作者
Guangguo Hao, Yaping Fu, Dongdong He, Xun Tuo, Shengmei Guo, Hu Cai
查看原文
摘要
An efficient and regioselective ipso-halogenation of diverse arylboronic acids with metal halide salts MX (X = I, Br) has been well established under electrochemical conditions. A gram-scale reaction has been performed to evaluate the applicability of the protocol. Cyclic voltammetry experiments indicated that the halide anion was oxidized prior to the arylboronic acid substrate under standard conditions.
相关文献
Changes in the electronic structure and properties of graphene induced by molecular charge-transfer
Rakesh Voggu, Chandra Sekhar Rout
2008-09-25
Communication
DOI: 10.1039/B808955H
Hydration of counterions in cation exchange resins studied by X-ray absorption fine structure
Makoto Harada, Tetsuo Okada
2008-09-10
Communication
DOI: 10.1039/B810997D
Surface-enhanced stereoselectivity in Mukaiyama aldol reactions catalyzed by clay-supported bis(oxazoline)–copper complexes
María J. Fabra, José M. Fraile, Clara I. Herrerías, Fernando J. Lahoz, José A. Mayoral, Ignacio Pérez
2008-09-19
Communication
DOI: 10.1039/B809956A
Asymmetric 1,3-dipolar cycloaddition with a P-stereogenic dipolarophile: An efficient approach to novel P-stereogenic 1,2-diphosphine systems
Nikolai Vinokurov, K. Michał Pietrusiewicz, Sławomir Frynas, Michael Wiebcke, Holger Butenschön
2008-09-12
Communication
DOI: 10.1039/B810573A
Separation of a diiminopyridine iron(ii) complex into rac- and meso- diastereoisomers provides evidence for a dual stereoregulation mechanism in propenepolymerization
Antonio Rodríguez-Delgado, Juan Cámpora, A. Marcos Naz, Pilar Palma, Manuel L. Reyes
2008-09-12
Communication
DOI: 10.1039/B810381J
Confined proteinadsorption into nanopore arrays fabricated by colloidal-assisted polymer patterning
Grazia M. L. Messina, Cristina Satriano, Giovanni Marletta
2008-09-05
Communication
DOI: 10.1039/B809664C
Photoactivatable HNO-releasing compounds using the retro-Diels–Alder reaction
Yusuke Adachi, Hidehiko Nakagawa, Kazuya Matsuo, Takayoshi Suzuki, Naoki Miyata
2008-09-23
Communication
DOI: 10.1039/B811985F
A novel type of N-formylation and related reactions of aminesviacyanides and esters as formylating agents
Kai Bao, Weige Zhang, Xiujuan Bu, Zhichun Song, Liang Zhang, Maosheng Cheng
2008-09-16
Communication
DOI: 10.1039/B810086A
One-pot synthesis of benzo[c]carbazoles by photochemical annulation of 2-chloroindole-3-carbaldehydes
Cailin Wang, Wei Zhang, Shenci Lu, Jingfei Wu, Zongjun Shi
2008-09-12
Communication
DOI: 10.1039/B808854C
Electron transfer in pristine and functionalised single-walled carbon nanotubes
Matteo Iurlo, Demis Paolucci, Massimo Marcaccio, Francesco Paolucci
2008-08-21
Feature Article
DOI: 10.1039/B809285K
您可能还喜欢
化合物问答
3 - （二氟甲基）-1 -氟苯(CAS号：26029-52-7)适用哪些法规指南？
3 - （二氟甲基）-1 -氟苯需遵循联合国全球化学品统一分类和标签制度（GHS），包括急性毒性、皮肤腐蚀/刺激、严重眼损伤/眼刺激等分类。同时，该化合物还需符...
26029-52-71-(Difluoromethyl)-3...
化合物问答
3,5-二甲基苯胺(CAS号：108-69-0)通常如何合成？
3,5-二甲基苯胺通常通过乙苯的氨解反应合成。反应中使用硫酸作为催化剂，反应温度为120-130°C。乙苯在硫酸存在下与氨反应，生成3,5-二甲基苯胺和苯胺副产...
108-69-03,5-Dimethylaniline
化合物问答
3-甲基异噻唑-5-胺(CAS号：24340-76-9)安全吗？
3-甲基异噻唑-5-胺在适当使用和储存条件下是相对安全的，但在操作时应注意防护措施。应避免吸入粉尘，避免与皮肤和眼睛直接接触。在操作过程中，应穿戴适当的防护装备...
24340-76-93-Methyl-1,2-thiazol...
化合物问答
3-(1,3-Thiazol-2-yl)-1H-indole(CAS号：135531-86-1)通常如何合成？
3-(1,3-噻唑-2-基)-1H-吲哚通常通过多步合成方法制备。首先，由噻唑-2-基溴化物和吲哚进行偶联反应，得到中间体。然后，通过还原反应将中间体转化为所需...
135531-86-13-(1,3-Thiazol-2-yl)...
化合物问答
4-溴-2-氟苯甲基氯(CAS号：85510-82-3)的主要用途是什么？
4-溴-2-氟苯甲基氯主要用于有机合成中间体，特别是在医药、农药和染料等领域。作为一种具有特定结构的化合物，它在合成复杂有机分子时扮演重要角色。
85510-82-34-Bromo-1-(chloromet...
化合物问答
处理Fmoc-β-(3-噻吩基)-D-Ala-OH(CAS号：220497-90-5)时应注意哪些实验室安全事项？
处理Fmoc-β-(3-噻吩基)-D-Ala-OH时，应佩戴防护手套、护目镜和实验服。操作应在通风橱内进行。如发生泄露，应立即用大量水冲洗，并通知实验室管理人员...
220497-90-5N-[(9H-Fluoren-9-ylm...
化合物问答
氮化硅(CAS号：12033-89-5)通常如何合成？
氮化硅通常通过氮化硅的直接反应合成，即在高温下将四氯化硅与氨气反应。具体步骤是将四氯化硅和氨气混合并加热至1300-1700℃，在该条件下，四氯化硅与氨气反应生...
12033-89-5Trisilicon tetranitr...
化合物问答
Cetirizine EP Impurity B DiHCl(CAS号：1000690-91-4)通常如何合成？
Cetirizine EP Impurity B DiHCl通常通过一锅法合成，首先将4-氯苯基-苯甲基氯甲酸酯与1-哌嗪乙酸反应，生成相应的酸，然后与盐酸反应...
1000690-91-4{4-[(4-Chlorophenyl)...
化合物问答
如何储存1-哌啶-4-基丁-1-酮(CAS号：3509-15-7)？
1-哌啶-4-基丁-1-酮应储存在阴凉、干燥的地方，避免阳光直射。存储容器应密封，并确保通风良好。建议储存温度不超过25℃，湿度保持在相对较低的水平。
3509-15-71-Piperidin-4-ylbuta...
化合物问答
如何处理含有VORUCICLIB(CAS号：1000023-04-0)的废料？
含有VORUCICLIB的废料应进行专业的收集和处理，包括使用适当的容器进行隔离，避免与其他化学品接触。处理方法通常包括化学中和、沉淀反应或吸附过程，随后进行焚...
1000023-04-02-[2-Chloro-4-(trifl...
来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
推荐化合物
![Pyrazolo[1,5-a]pyridine-3-carbothioamide structure](https://cnstatic.chemtradehub.com/structs/885/885275-44-5-aae0.webp "Pyrazolo[1,5-a]pyridine-3-carbothioamide structure")
推荐供应商
免责声明
本页面提供的学术期刊信息仅供参考和研究使用。我们与任何期刊出版商均无关联，也不处理投稿事宜。如有投稿相关咨询，请直接联系相关期刊出版商。
如发现页面信息有误，请发送邮件至 support@chemtradehub.com 联系我们。我们将及时核实并处理您的问题。