![N-[(9Z)-9-Octadecen-1-yl]-1,3-propanediamine structure](https://cnstatic.chemtradehub.com/structs/717/7173-62-8-d43e.webp "N-[(9Z)-9-Octadecen-1-yl]-1,3-propanediamine structure")
Methanol production from CO2via an integrated, formamide-assisted approach
文献信息
发布日期
2020-01-07
DOI
10.1039/C9SE01141B
影响因子
6.367
作者
Aswin Gopakumar, Tim Pfister, Gunay Imanzade, Gabriela Gastelu, Paul J. Dyson
查看原文
摘要
The synthesis of fuels from CO2 has made tremendous progress in recent years, although practical applications remain limited. Herein, we describe a cyclic process that produces MeOH from CO2via formamide intermediates, which are initially reduced using NaBH4 to form methanol and concomitantly release the corresponding amine, from which the formamide is subsequently regenerated in the presence of CO2/NaBH4. By tuning the substituents on the formamide/amine, the selectivity of both steps can be controlled, allowing the process to proceed in high yields, either in two separate steps or in a single step process. The observed trends in reactivity were rationalized with a resonance model of the formamide, which supports the observed trends in reactivity, and further consolidated by spectroscopy and calculations.
期刊推荐
Critical Reviews in Solid State and Materials Sciences
Journal of Chemical Sciences
Heteroatom Chemistry
Bioorganic & Medicinal Chemistry Letters
Acta Metallurgica Sinica-English Letters
Herald of the Russian Academy of Sciences
Medicinal Chemistry Research
Atomization and Sprays
Chinese Journal of Chemistry
Journal of Asian Natural Products Research
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