Ring opening polymerization of macrocyclic oligoesters derived from renewable sources

文献信息

发布日期 2020-03-17

DOI 10.1039/D0PY00258E

影响因子 5.582

作者

Antxon Martínez de Ilarduya, Sebastián Muñoz Guerra

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摘要

Macrocyclic oligoesters (MCOs) derived from biomass such as those prepared from alkylene alkanedioates and 2,5-furandicarboxylates are suitable compounds for ring opening polymerization (ROP) to produce high molecular weight bio-based polyesters. The synthetic procedures that have been recently developed to obtain these MCOs in good yields, their ROP either alone or together with other cyclic compounds, and their recovery by cyclodepolymerization of the final polyesters are the main topics covered in this review. Both organometallic compounds and enzymes such as Candida antarctica lipase B are the catalytic systems used for all reactions. This synthetic approach based on ROP of MCOs derived from renewable sources opens a green pathway for a circular economy in plastics.

期刊推荐

Organic Letters

Organic & Biomolecular Chemistry

Current Topics in Medicinal Chemistry

Current Organic Synthesis

Letters in Drug Design & Discovery

Letters in Organic Chemistry

Catalysis Communications

Phytochemistry Reviews

Physics of Life Reviews

Nature Methods

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Ring opening polymerization of macrocyclic oligoesters derived from renewable sources

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