Radical generation from electroreduction of aryl and benzyl ammonium salts: synthesis of organoboronates
文献信息
发布日期
2020-12-12
DOI
10.1039/D0QO00979B
影响因子
5.281
作者
Long Lin, Qianjin Chen, Bo Xu
查看原文
摘要
We report a direct electrocatalytic borylation of aryl and benzyl trimethylammonium salts with bis(pinacolato)diboron at room temperature. The protocol is compatible with substrates bearing a variety of functional groups, including halides (Cl and Br), which are not tolerated by previously reported methods involving nickel catalysis or photocatalysis. The protocol does not require stoichiometric metals, external reducing agents, or sacrificial anodes and can be carried out on a gram scale.
相关文献
A triple-stranded helicate and mesocate from the same metal and ligand
Zhan Zhang, David Dolphin
2009-10-21
Communication
DOI: 10.1039/B913231G
Strategies for the synthesis of bioactive pyran naphthoquinones
Vitor Francisco Ferreira, Sabrina Baptista Ferreira, Fernando de Carvalho da Silva
2010-09-13
Perspective
DOI: 10.1039/C0OB00277A
Highly ordered TiN nanotube arrays as counter electrodes for dye-sensitized solar cells
Q. W. Jiang, G. R. Li, X. P. Gao
2009-09-25
Communication
DOI: 10.1039/B912776C
Raman spectroscopy of strained single-walled carbon nanotubes
Zhongfan Liu, Jin Zhang, Bo Gao
2009-10-07
Feature Article
DOI: 10.1039/B914588E
Organocatalytic kinetic resolution via intramolecular aldol reactions: Enantioselective synthesis of both enantiomers of chiral cyclohexenones
Liujuan Chen, Sanzhong Luo, Jiuyuan Li, Xin Li, Jin-Pei Cheng
2010-04-01
Paper
DOI: 10.1039/B927343C
Synthesis of 3-amino-thiochromanes from 4-benzyl 2-thiazolines, via an unprecedented intramolecular electrophilic aromatic substitution
Guillaume Mercey, Remi Legay, Jean-François Lohier, Jana Sopkova-de Oliveira Santos, Jocelyne Levillain, Annie-Claude Gaumont, Mihaela Gulea
2010-04-22
Communication
DOI: 10.1039/C003050C
Hydroxylation of benzophenone with ammonium phosphomolybdate in the solid state via UV photoactivation
Mrinmoyee Basu, Suresh Sarkar, Surojit Pande, Subhra Jana, Arun Kumar Sinha, Sougata Sarkar, Mukul Pradhan, Anjali Pal, Tarasankar Pal
2009-10-15
Communication
DOI: 10.1039/B905718H
Intrinsic acidity and electrophilicity of gaseous propargyl/allenyl carbocations
Priscila M. Lalli, Yuri E. Corilo, Patrícia V. Abdelnur, Marcos N. Eberlin
2010-03-29
Paper
DOI: 10.1039/C001985B
Silver nanoparticles with planar twinned defects: effect of halides for precise tuning of plasmon resonance maxima from 400 to >900 nm
Nicole Cathcart, Andrew J. Frank, Vladimir Kitaev
2009-10-15
Communication
DOI: 10.1039/B916902D
Highly selective fluorescent probe for Au3+ based on cyclization of propargylamide
Min Jung Jou, Xiaoqiang Chen, Ha Na Kim, Hae-Jo Kim, Sang-gi Lee
2009-10-22
Communication
DOI: 10.1039/B917832E
您可能还喜欢
化合物问答
如何处理含有8-氯咪唑并[1,2-A]吡嗪(CAS号：69214-33-1)的废料？
处理含有8-氯咪唑并[1,2-A]吡嗪的废料时，应首先将其收集并进行化学回收或降解。如果无法回收，需采用安全的化学处理方法，如中和、氧化还原或沉淀。处理过程中需...
69214-33-18-chloroimidazo[1,2-...
化合物问答
Calhex 231 hydrochloride(CAS号：2387505-78-2)适用哪些法规指南？
Calhex 231 hydrochloride 需要遵循《全球化学品统一分类和标签制度》（GHS）的分类和标签要求，以及欧盟的《化学品注册、评估、授权和限制条...
2387505-78-24-Chloro-N-[(1S,2S)-...
化合物问答
11-Beta,17-alpha,21-三羟基-5-beta-孕烯-3,20-二酮(CAS号：1482-50-4)的物理化学性质是什么？
11-Beta,17-alpha,21-三羟基-5-beta-孕烯-3,20-二酮是一种无色结晶性粉末，分子量为372.45 g/mol。该化合物在水中的溶解度...
1482-50-45β-Dihydrocortisol
化合物问答
处理5-异丙基-1,3,4-恶二唑-2-羧酸(CAS号：944907-13-5)时应注意哪些实验室安全事项？
处理5-异丙基-1,3,4-恶二唑-2-羧酸时应注意以下安全事项：穿戴适当的个人防护装备，包括实验室外套、手套和护目镜；操作应在通风橱中进行，以减少吸入或接触有...
944907-13-55-Isopropyl-1,3,4-ox...
化合物问答
benzyl 3-bromopropanoate(CAS号：90841-55-7)安全吗？
Benzyl 3-bromopropanoate属于有毒物质，吸入、摄入或皮肤接触均可能对人体造成伤害。操作时应佩戴防护眼镜、口罩和手套，避免吸入蒸汽和直接接触...
90841-55-7Benzyl 3-bromopropan...
化合物问答
什么是(R)-N-苄氧羰基-3,4-二氢-1H-异喹啉羧酸(CAS号：151004-88-5)？
(R)-N-苄氧羰基-3,4-二氢-1H-异喹啉羧酸是一种含有苄氧羰基和异喹啉环结构的化合物，分子式为C17H15NO3。它是一种有机化合物，具有一定的生物活性...
151004-88-5(1R)-2-[(Benzyloxy)c...
化合物问答
在合成中是否有1-苄基吡啶嗡-3-羧酸盐(CAS号：15990-43-9)的替代品？
可以考虑使用1-苄基吡啶-3-羧酸盐作为1-苄基吡啶嗡-3-羧酸盐的替代品。此外，还可以探索其他类似物，如1-苄基吡啶-3-氨基甲酸酯等。具体的替代品选择需根据...
15990-43-91-Benzyl-3-pyridiniu...
化合物问答
(2,6-二甲基吡啶-3-基)甲醇(CAS号：582303-10-4)安全吗？
(2,6-二甲基吡啶-3-基)甲醇在使用时需注意安全，应避免吸入其蒸汽，接触皮肤和眼睛。操作应在通风良好的环境中进行，佩戴适当的个人防护装备。
582303-10-4(2,6-Dimethyl-3-pyri...
化合物问答
5-溴-2-乙烯基吡啶(CAS号：226883-52-9)的物理化学性质是什么？
5-溴-2-乙烯基吡啶是一种有机化合物，外观为白色固体，具有良好的结晶性。分子量约为190.03 g/mol。它的溶解性在水中较差，但在有机溶剂如二氯甲烷、甲醇...
226883-52-95-Bromo-2-vinylpyrid...
化合物问答
2-羟基-3-硝基-5-甲基吡啶(CAS号：7464-14-4)应用于哪些行业？
2-羟基-3-硝基-5-甲基吡啶主要应用于医药、聚合物和半导体行业。在医药领域，它可以用作合成其他药物的中间体。在聚合物领域，它可以作为功能性单体参与聚合反应，...
7464-14-45-Methyl-3-nitro-2(1...
来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
推荐化合物
![6-Bromo-2,3-dihydro-1H-pyrido[2,3-b][1,4]oxazine structure](https://cnstatic.chemtradehub.com/structs/120/1203499-17-5-b4d1.webp "6-Bromo-2,3-dihydro-1H-pyrido[2,3-b][1,4]oxazine structure")
![[4-(Isobutyrylamino)phenyl]boronic acid structure](https://cnstatic.chemtradehub.com/structs/874/874219-50-8-6ab5.webp "[4-(Isobutyrylamino)phenyl]boronic acid structure")
推荐供应商
免责声明
本页面提供的学术期刊信息仅供参考和研究使用。我们与任何期刊出版商均无关联，也不处理投稿事宜。如有投稿相关咨询，请直接联系相关期刊出版商。
如发现页面信息有误，请发送邮件至 support@chemtradehub.com 联系我们。我们将及时核实并处理您的问题。