Copper-catalyzed borylative cyclization of γ,δ-unsaturated aromatic oxime esters to (borylmethyl)pyrrolidines

文献信息

发布日期 2020-09-17
DOI 10.1039/D0QO01064B
影响因子 5.281
作者

Youcan Zhang


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摘要

An efficient copper-catalyzed aminoborylation of γ,δ-unsaturated aromatic oxime esters with bis(pinacolato)diboron has been developed. A variety of α-(borylmethyl)pyrrolidine derivatives were constructed in high yields under mild conditions. Notably, examples of converting the obtained aminoborylated product, including cycloaddition, oxidation, and coupling reactions, have been given as well.

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Organic Chemistry Frontiers

Organic Chemistry Frontiers
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