Structure-dependent iron-based metal–organic frameworks for selective CO2-to-CH4 photocatalytic reduction

文献信息

发布日期 2020-11-13
DOI 10.1039/D0TA10278D
影响因子 12.732
作者

Xiao-Yao Dao, Jin-Han Guo, Xiao-Yu Zhang, Shi-Qing Wang, Xiao-Mei Cheng, Wei-Yin Sun


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摘要

Visible-light driven reduction of carbon dioxide (CO2) to methane (CH4) is a challenge in the photocatalytic reaction system. Herein, two Fe-based metal–organic frameworks (MOFs) MIL-100(Fe) and MIL-101(Fe) with single-trimetallic clusters but distinct organic ligands were employed to explore the structure-dependent CO2 conversion performance. Compared with MIL-101(Fe), MIL-100(Fe) exhibits superior catalytic activity and selectivity for CH4 generation under visible-light irradiation via a solvent-free route. This is the first report that MIL-100(Fe) finishes the photoreduction of CO2 into CH4. Importantly, the plausible conversion pathways of the reaction were given by density functional theory (DFT) calculations. This work furnishes new direction for constructing MOFs to achieve CO2-to-CH4 conversion.

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来源期刊

Journal of Materials Chemistry A

Journal of Materials Chemistry A
CiteScore: 19.5
自引率: 4.7%
年发文量: 2211

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment

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