A sequential ROMP strategy to donor–acceptor di-, tri- and tetra arylenevinylene block copolymers
文献信息
发布日期
2021-11-15
DOI
10.1039/D1PY01202A
影响因子
5.582
作者
Venukrishnan Komanduri, Yurachat Janpatompong, Raymundo Marcial-Hernandez, Daniel J. Tate, Michael L. Turner
查看原文
摘要
The synthesis of donor–acceptor di-, tri- and tetrablock copolymers via sequential ROMP of electron rich and electron deficient paracyclophanediene monomers using Grubbs ruthenium carbene initiator, G3, is discussed. Block copolymers were initially formed with a cis/trans alkene geometry and these can be readily photoisomerised to the all trans forms. The optical and electrochemical properties of these block copolymers were examined by theory and experiment, and it was found that the HOMO and LUMO energy levels are localised on the donor and acceptor blocks, respectively.
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来源期刊
Polymer Chemistry
CiteScore:
8.6
自引率:
7.3%
年发文量:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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