Highly chemoselective hydrogenation of cyclic imides to ω-hydroxylactams or ω-hydroxyamides catalyzed by iridium catalysts

文献信息

发布日期 2021-09-30

DOI 10.1039/D1QO01100F

影响因子 5.281

作者

Jiang Wang, Xumu Zhang, Runtong Zhang, Baode Ma

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摘要

Several novel ferrocene-based PNN ligands were prepared, which were found to be highly effective catalysts (TON up to 50 000) for the homogeneous hydrogenation of cyclic imides with iridium. The hydrogenation mode (type I: ring opening/type II: non-ring opening) could be finely tuned by tiny changes in the ligands. Using this straightforward strategy, a plethora of ω-hydroxylactams and ω-hydroxyamides with different functional groups were obtained in high yield.

期刊推荐

Proceedings of the National Academy of Sciences of the United States of America

Fibre Chemistry

Molecular Pharmacology

Journal of Heterocyclic Chemistry

European Journal of Wood and Wood Products

Science Progress

Journal of Medicinal Chemistry

Pure and Applied Chemistry

Russian Chemical Reviews

Israel Journal of Chemistry

来源期刊

Organic Chemistry Frontiers

CiteScore: 7.8

自引率: 8.7%

年发文量: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Highly chemoselective hydrogenation of cyclic imides to ω-hydroxylactams or ω-hydroxyamides catalyzed by iridium catalysts

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