Regiospecific and site-selective C–H allylation of phenols with vinyldiazo compounds catalyzed by In(iii)

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发布日期 2021-09-10

DOI 10.1039/D1QO01184G

影响因子 5.281

作者

Dan Zhao, Jingyan Luo, Lu Liu

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摘要

Metal-catalyzed C–H functionalization is one of the most effective methods to form a C–C bond. We herein report a highly regiospecific, site-selective, and C–H chemoselective substitution reaction of phenols with alkenyl diazo compounds catalyzed by commercially available and low-cost In(OTf)3. The reactions of aryl or alkyl substituted vinyldiazoacetates provided the corresponding phenol-allylation products in different regioselective and site-selective manners.

期刊推荐

Journal of Physics and Chemistry of Solids

Journal of Catalysis

Journal of Heterocyclic Chemistry

Russian Chemical Reviews

Helvetica Chimica Acta

Science

Science Progress

Proceedings of the National Academy of Sciences of the United States of America

Fibre Chemistry

Organic Preparations and Procedures International

来源期刊

Organic Chemistry Frontiers

CiteScore: 7.8

自引率: 8.7%

年发文量: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Regiospecific and site-selective C–H allylation of phenols with vinyldiazo compounds catalyzed by In(iii)

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来源期刊

Organic Chemistry Frontiers

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