The effect of PbS quantum dots on molecular dynamics and conductivity of PTB7:PC71BM bulk heterojunction as revealed by dielectric spectroscopy

文献信息

发布日期 2022-03-30

DOI 10.1039/D2CP00770C

影响因子 3.676

作者

Mihai Asandulesa, Sergei Kostromin, Alexey Aleksandrov, Alexey Tameev, Sergei Bronnikov

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摘要

A ternary photovoltaic blend containing the PTB7 donor component, the PC71BM acceptor component, and colloidal quantum dots of lead sulfide (PbS QDs) was investigated using broadband dielectric spectroscopy. In the dielectric loss spectrum of PTB7:PC71BM:PbS QDs, γ- and β-relaxation processes in PTB7 were recognized and analyzed in terms of Arrhenius-type equations. To elucidate the effect of PbS QDs on molecular dynamics of PTB7, the activation energies of both processes were evaluated and compared with those obtained for the binary PTB7:PC71BM blend. Using the CELIV method, the charge carrier mobility was estimated. The PbS QD incorporation into the binary blend was shown to decrease both electron and hole mobility in the ternary PTB7:PC71BM:PbS QD blend. For evaluating the charge carrier lifetime in the ternary blend, the Cole–Cole diagrams derived from the dc conductivity data were plotted. The charge carrier lifetime was found to be much less than the hole extraction time, thus providing effective accumulation of charge carries at the electrodes in the ternary blend under investigation.

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来源期刊

Physical Chemistry Chemical Physics

CiteScore: 5.5

自引率: 10.3%

年发文量: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.