Solvent-controlled synthesis of hydrophilic and hydrophobic carbon dots
文献信息
Chenhan Zhang, Zhihua Ying, Yuan Jiang, Haiyang Wang, Xuebin Zhou, Weipeng Xuan, Peng Zheng
Hydrophilicity and hydrophobicity are of paramount importance in surface chemistry. In this study, a solvent-controlled synthesis of hydrophilic and hydrophobic carbon dots (CDs) was prepared via a solvothermal process using pentafluorobenzyl alcohol as the carbon source in either deionized water or N,N-dimethylformamide (DMF) medium. By simply varying the reaction solvent to control the doping of nitrogen and fluorine elements, the hydrophilicity or hydrophobicity of the CDs could be regulated. Hydrophobic and hydrophilic CDs showed blue and green light under a UV lamp, respectively. Besides, we regulated the volume ratio of water/DMF (1 : 2, 1 : 1 and 2 : 1) in the reaction solvent to prepare amphiphilic CDs and further studied their hydrophilicity and hydrophobicity. Furthermore, the sensitivity of hydrophobic CDs to water was investigated. In water detection, the photoluminescent intensity of the blue peak and green peak showed high linearity within the water content of 4–80% and 10–80%, respectively (limit of detection = 0.08%, v/v, in DMF).
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











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