Recent advances in ambient electrochemical methane conversion to oxygenates using metal oxide electrocatalysts

文献信息

发布日期 2023-12-06
DOI 10.1039/D3GC03513A
影响因子 10.182
作者

Fengli Liu, Yong Yan, Ge Chen, Dong Wang


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摘要

To reach a decarbonized future, the conversion of greenhouse gases into green fuels and valuable chemicals is of crucial importance. Methane emissions are the second most significant contributor to global warming. Recent advances in electrocatalytic partial oxidation of methane to high-value fuels at ambient temperatures promise to sidestep the requirement of high temperature in conventional thermal catalysis and provide a revolutionary, sustainable, and decentralized alternative to flaring. Electrocatalysts that can selectively produce valuable compounds from methane under mild conditions are essential for commercialization. This review covers current developments in the electrochemical partial oxidation of methane to oxygenates, with an emphasis on metal oxide electrocatalysts. The regularly deployed strategies, including doping and interface engineering, are systematically reviewed in detail. In addition, the design of the electrolytic cell, the electrolyte, time, potential, and temperature are examined thoroughly and discussed.

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Green Chemistry

Green Chemistry
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Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.

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