Tunable emissions in lanthanide-based supramolecular metallogels

文献信息

发布日期 2023-11-15

DOI 10.1039/D3NJ04692C

影响因子 3.591

作者

Eun Gyu Lee, Hyeon min Han, Jong Hwa Jung, Sung Ho Jung

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摘要

We have developed a tunable emissive supramolecular metallo-gel functionalized with lanthanide coordination bonds using a low molecular weight gelator 1 having terminal terpyridine. In the presence of Tb(III) and Eu(III) ions, the coordination of lanthanides to gelator 1 results in green and red emissive supramolecular metallogels, respectively. A supramolecular growth mechanism of 1-Tb that follows an isodesmic model has been observed, relying on delicate balances between non-covalent interactions. Furthermore, controlling the stoichiometry of lanthanide metal ions with respect to 1 : Tb(III) : Eu(III) leads to yellow and white light-emitting supramolecular bimetallic gels.

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来源期刊

New Journal of Chemistry

CiteScore: 5.3

自引率: 3.7%

年发文量: 2153

NJC (New Journal of Chemistry) is a broad-based primary journal encompassing all branches of chemistry and its sub-disciplines. It contains full research articles, communications, perspectives and focus articles. This well-established journal, owned by the Centre National de la Recherche Scientifique (CNRS) of France, has been co-published with the Royal Society of Chemistry since January 1998. NJC is the forum for the publication of high-quality, original and significant work that opens new directions in chemistry or other scientific disciplines. In addition to having a significant chemical component, work published in NJC must demonstrate that it will have an impact on areas of research other than that of the reported work.

Tunable emissions in lanthanide-based supramolecular metallogels

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来源期刊

New Journal of Chemistry

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