Metal-free hydrophosphorodithiolation of alkynes with P4S10 and alcohols leading to vinyl phosphorodithioates

文献信息

发布日期 2023-11-23

DOI 10.1039/D3QO01588B

影响因子 5.281

作者

Yalu Wang, Yufen Lv, Huilan Yue, Dong Yi

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摘要

A simple and metal-free strategy has been developed for the construction of vinyl phosphorodithioates via direct hydrophosphorodithiolation of alkynes with P4S10 and alcohols. This three-component reaction could be conducted under mild conditions to access a variety of vinyl phosphorodithioates with Z-isomers as the major products without the use of any metal reagents, ligands, or additives. Preliminary mechanistic studies suggested that a radical process was involved in this reaction procedure.

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来源期刊

Organic Chemistry Frontiers

CiteScore: 7.8

自引率: 8.7%

年发文量: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry