Advanced electrolyte with high stability and low-temperature resistance for zinc-ion batteries
文献信息
Qixian Bai, Qi Meng, Weiping Liu, Wenjun Lin, Pengfei Yi, Jingjing Tang, Guilin Zhang, Penghui Cao, Juan Yang
Aqueous zinc-ion batteries (AZIBs) are considered to be a green and safe energy storage system. However, electrolyte leakage, zinc dendrite growth and side reactions are still barriers to their practical application. A quasi-solid sodium alginate gel electrolyte (GE) was designed to alleviate these pain points. To further stabilize the water molecules in this GE and extend its application to subzero temperatures, a disaccharide called trehalose (TreH) was introduced as a multifunctional additive. The rational introduction of TreH notably improved the strength (186.6 kPa) of the sodium alginate GE while retaining a high ionic conductivity (22.4 mS cm−1) at 25 °C. The zinc–polyaniline full battery assembled with this composite GE exhibited a capacity retention of 70.4% after 500 cycles at 25 °C, and still delivered a reversible capacity of 120.6 mA h g−1 at −20 °C. These results show that the sodium alginate GE with trehalose as an additive has great potential for development in AZIBs.
期刊推荐

Bioorganic & Medicinal Chemistry

Atomization and Sprays

Chinese Journal of Chemistry

Bioorganic & Medicinal Chemistry Letters

Medicinal Chemistry Research

Colloid Journal

Critical Reviews in Solid State and Materials Sciences

Journal of Chemical Sciences

Acta Metallurgica Sinica-English Letters

Topics in Catalysis
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来源期刊
Journal of Materials Chemistry A

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment




