The role of intersystem crossing in the deactivation of the singlet excited aminofluorenones
文献信息
László Biczók, Tibor Bérces, Tomoyuki Yatsuhashi, Hiroshi Tachibana, Haruo Inoue
Solvent and substituent effects on the competition between internal conversion and triplet formation were studied systematically for aminofluorenones and their N-methylated derivatives. Intersystem crossing (ISC) was found to be the dominant process for the singlet excited 1-amino- and 1-methylaminofluorenone in all solvents. The short fluorescence decay time of these compounds does not originate from intramolecular hydrogen bonding induced internal conversion but it is due to the fast triplet formation. Rather slow (kISC⩽4.8 × 107 s−1) and solvent insensitive intersystem crossing characterizes the photophysical behavior of 2-, 3- and 4-aminofluorenones but their internal conversion rate strongly increases with solvent polarity. The change of the internal conversion rate constants with molecular structure and solvent can be rationalized in terms of the energy gap law.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














