A mechanistic rationalization of unusual kinetic behavior in proline-mediated C–O and C–N bond-forming reactions
文献信息
Suju P. Mathew, Martin Klussmann, Hiroshi Iwamura, David H. Wells, Jr., Alan Armstrong
Kinetic evidence supports the role of the reaction product in the catalytic cycle of proline-mediated α-aminoxylation and α-amination reactions, providing both design principles as well as a model for the evolution of efficiency in catalysis.
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Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry











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