Sulfate ion encapsulation in caged supramolecular structures assembled by second-sphere coordination
文献信息
Jianjun Liang, Jin Yang, Chuandong Jia, Hongrui Zhang, Ning Tang, Christoph Janiak
A tripodal tris(3-pyridylurea) receptor (L) assembles with metal sulfate salts MSO4 (M = Mn, Zn) to afford supramolecular cages [SO4⊂L2] that encapsulate the SO42− ion via multiple hydrogen bonds in a three-dimensional structure held by second-sphere coordination; 1H NMR and negative-ion mode ESI-MS spectra reveal significantly strong sulfate binding in solution.
相关文献
Reactions of hydrophobic organic nanoparticle mixtures in water: nanoparticle-on-nanoparticle oxidative dye bleaching
Marco Giardiello, Tom O. McDonald, Jet-Sing Lee, Aled D. Roberts, Andrew Owen, Steve P. Rannard
DOI: 10.1039/C3GC40573G
Preparation of PDMS membrane using water as solvent for pervaporation separation of butanol–water mixture
Shufeng Li, Fan Qin, Peiyong Qin, M. Nazmul Karim, Tianwei Tan
DOI: 10.1039/C3GC40291F
Efficient and recyclable rare earth-based catalysts for Friedel–Crafts acylations under microwave heating: dendrimers show the way
DOI: 10.1039/C3GC40720A
Tungstate based poly(ionic liquid) entrapped magnetic nanoparticles: a robust oxidation catalyst
Ali Pourjavadi, Seyed Hassan Hosseini, Firouz Matloubi Moghaddam, Behzad Koushki Foroushani, Craig Bennett
DOI: 10.1039/C3GC41307A
On the solubility of wood in non-derivatising ionic liquids
Lasse Kyllönen, Arno Parviainen, Somdatta Deb, Martin Lawoko, Mikhail Gorlov, Ilkka Kilpeläinen, Alistair W. T. King
DOI: 10.1039/C3GC41273C
Evaluation of deep eutectic solvent–water binary mixtures for lipase-catalyzed lipophilization of phenolic acids
Erwann Durand, Jérôme Lecomte, Bruno Baréa, Eric Dubreucq, Robert Lortie, Pierre Villeneuve
DOI: 10.1039/C3GC40899J
Highly efficient production of lactic acid from cellulose using lanthanide triflate catalysts
Fen-Fen Wang, Chun-Ling Liu, Wen-Sheng Dong
DOI: 10.1039/C3GC40836A
Ionic liquid forms of the herbicide dicamba with increased efficacy and reduced volatility
O. Andreea Cojocaru, Julia L. Shamshina, Gabriela Gurau, Anna Syguda, Tadeusz Praczyk, Juliusz Pernak, Robin D. Rogers
DOI: 10.1039/C3GC37143C
Retracted Article: One-pot synthesis of glycidol from glycerol and dimethyl carbonate over a highly efficient and easily available solid catalyst NaAlO2
Rongxian Bai, Hongkun Zhang, Fuming Mei, Shu Wang, Tao Li, Guangxing Li
DOI: 10.1039/C3GC40855H
您可能还喜欢
如何储存8-溴-4-羟基-6-(三氟甲氧基)喹啉-3-羧酸乙酯(CAS号:1072944-81-0)?
8-溴-4-羟基-6-(三氟甲氧基)喹啉-3-羧酸乙酯应储存在阴凉、干燥的地方,避免光照和高温。建议使用密封容器进行储存,以防止水分和空气的影响。
2,2-二(2-呋喃基)丙烷(CAS号:17920-88-6)的市场或研究趋势如何?
2,2-二(2-呋喃基)丙烷的研究趋势主要集中在新型材料的开发和应用,如高分子材料、有机光电材料等。市场趋势方面,随着环保要求的提高和新材料的应用,该化合物的需...
如何处理含有螺[呋喃并[3,4-b]吡啶-5(7H),4'-哌啶]-7-酮盐酸盐(CAS号:475152-31-9)的废料?
对于含有螺[呋喃并[3,4-b]吡啶-5(7H),4'-哌啶]-7-酮盐酸盐的废料,应首先进行分类和分离,以减少危险物质的数量。随后,可以考虑通过化学氧化、生物...
Cinnamyl 3-aminobut-2-enoate(CAS号:113898-97-8)安全吗?
Cinnamyl 3-氨基丁-2-烯酸在接触皮肤和眼睛时可能会引起刺激。应避免吸入其粉尘和烟雾。操作时应穿戴适当的个人防护装备,如手套、护目镜和实验室外套。
反式-2-十二碳烯二酸(CAS号:6402-36-4)的市场或研究趋势如何?
反式-2-十二碳烯二酸在医药、材料科学等领域有一定的应用,但其市场相对较小。近年来,由于环保意识的提升,对环境友好型化学品的需求增加,研究倾向于开发更绿色的合成...
什么是(9ci)-1H-苯并咪唑-5-乙酸(CAS号:473895-86-2)?
(9ci)-1H-苯并咪唑-5-乙酸是一种含氮杂环化合物,其化学结构为1H-苯并咪唑-5-乙酸。该化合物具有特定的分子式C8H7NO2,属于有机酸类化合物。
酞菁蓝(CAS号:147-14-8)的主要用途是什么?
酞菁蓝主要用作颜料和染料,广泛应用于塑料、油墨、涂料、纺织品及橡胶工业中。它也用于光敏材料,如太阳能电池和光刻胶。在医疗领域,酞菁蓝因其光敏特性被用于某些光动力...
5-甲基-1,2,3,4-四氢异喹啉(CAS号:123593-99-7)安全吗?
5-甲基-1,2,3,4-四氢异喹啉在使用和储存时需要谨慎处理。它具有一定的毒性,应避免吸入其蒸气或直接接触皮肤和眼睛。操作此化合物时,建议佩戴防护眼镜、实验服...
如何处理含有3',4',5'-三甲氧基苯乙酮(CAS号:1136-86-3)的废料?
含有3',4',5'-三甲氧基苯乙酮的废液应首先确保其是否为危险废物,根据当地法规确定处理方法。通常,这类有机废液可以采用中和反应降低其pH值,然后通过蒸馏或萃...
如何储存KI-7(CAS号:1489263-00-4)?
KI-7应储存在通风良好的干燥环境中,避免光照和高温。建议使用密封容器储存,并保持在阴凉处。储存温度应控制在室温范围内,一般建议不超过25°C。避免与氧化剂接触...
来源期刊
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry














