Hydrogen bonding directs the H2O2oxidation of platinum(ii) to a cis-dihydroxo platinum(iv) complex ‡
文献信息
Russell A. Taylor, David J. Law, Glenn J. Sunley, Andrew J. P. White, George J. P. Britovsek
The use of ligands with proximate hydrogen bonding substituents in the oxidation of platinum(II) dimethyl complexes with H2O2 leads to the exclusive formation of an unusual cis-dihydroxo platinum(IV) complex, which can dehydrate to form a trinuclear metalla-azacrown complex.
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