Stacking of double bonds for photochemical [2+2] cycloaddition reactions in the solid state
文献信息
发布日期
2008-09-01
DOI
10.1039/B809136F
影响因子
6.222
作者
Mangayarkarasi Nagarathinam, Abdul Malik Puthan Peedikakkal, Jagadese J. Vittal
查看原文
摘要
trans-1,2-Bis(4-pyridyl)ethylene (bpe), containing a CC bond, has been extensively studied for solid-state photochemical [2+2] cycloaddition reactions, in discrete molecular and metal complexes, hydrogen bonded and coordination polymeric structures. The challenges in orienting a pair or more of bpe molecules in the solid-state using crystal engineering principles, and their photochemical behaviour and implications, based on Schmidt’s postulates, are discussed.
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来源期刊
Chemical Communications
CiteScore:
8.6
自引率:
4.7%
年发文量:
2458
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