Activated carbonates: enabling the synthesis of differentiated polycarbonate resins via melt transcarbonation

文献信息

发布日期 2016-08-05

DOI 10.1039/C6PY00925E

影响因子 5.582

作者

T. Hoeks, E. Kung, J. P. Lens, P. J. McCloskey, B. A. J. Noordover, J. P. A. Heuts

查看原文

摘要

Activated carbonates facilitate the preparation of polycarbonates based on monomers that are unsuitable for traditional melt polymerization at high temperatures. Bis(methyl salicyl) carbonate (BMSC) clearly shows reactivity benefits over diphenyl carbonate in melt polymerization reactions, resulting in shorter reaction times and reduced heat exposure during polymerization. The increased reactivity enables the melt polymerization of a wide range of monomers, as demonstrated by two examples using volatile resorcinol and sterically hindered tert-butyl hydroquinone as monomers in the preparation of (co)polycarbonates.

期刊推荐

Bioorganic Chemistry

Tetrahedron

Pharmacology & Therapeutics

Progress in Materials Science

Annual Review of Public Health

European Journal of Medicinal Chemistry

Journal of Dispersion Science and Technology

Pharmaceutical Chemistry Journal

Dental Materials

Drug and Chemical Toxicology

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Activated carbonates: enabling the synthesis of differentiated polycarbonate resins via melt transcarbonation

文献信息

期刊推荐

相关文献

Phosphonated furan-functionalized poly(ethylene oxide)s using orthogonal click chemistries: synthesis and Diels–Alder reactivity

One-pot two polymers: ABB′ melt polycondensation for linear polyesters and hyperbranched poly(ester-urethane)s based on natural l-amino acids

Modification of block copolymer vesicles: what will happen when AB diblock copolymer is block-extended to an ABC triblock terpolymer?

O-Nitrobenzyl-alt-(phenylethynyl)benzene copolymer-based nanoaggregates with highly efficient two-photon-triggered degradable properties via a FRET process

Facile anionic synthesis of a well-controlled thermally cross-linkable block copolymer for polymer-based resistive memory device applications

A new pathway towards polymer modified cellulose nanocrystals via a “grafting onto” process for drug delivery

Back cover

Benzobisthiadiazole-alt-bithiazole copolymers with deep HOMO levels for good-performance field-effect transistors with air stability and a high on/off ratio

Effect of gold nanoparticle shapes for phototherapy and drug delivery

Far-red/near-infrared fluorescent conjugated polymer nanoparticles with size-dependent chirality and cell imaging applications

您可能还喜欢

如何储存1,2-环己二酮环乙缩醛(CAS号：4746-96-7)？

Ecopladib(CAS号：381683-92-7)的市场或研究趋势如何？

2,3-Dimethyl-3H-imidazo[4,5-c]pyridine(CAS号：52538-09-7)通常如何合成？

2,3,4,5-tetrahydro-1H-3-苯并氮杂环;盐酸盐(CAS号：17379-01-0)的市场或研究趋势如何？

解草嗪(CAS号：68-90-6)安全吗？

如何储存盐酸甘氨酸丁酯(CAS号：13048-99-2)？

什么是2-Iodo-N,N-dimethylbenzamide(CAS号：54616-46-5)？

如何储存2-氨基-N-环己基乙酰胺(CAS号：16817-90-6)？

5-溴-2-(4H-1,2,4-三唑-4-基)吡啶(CAS号：959240-99-4)的市场或研究趋势如何？

2,4-二溴-6-三氟甲基嘧啶(CAS号：785778-00-9)通常如何合成？

来源期刊

Polymer Chemistry

推荐化合物

Methyl 2-hydroxydodecanoate

2,2',3,3',4,5,5',6,6'-Nonabromobiphenyl

6-CHLORO-2,3-DIOXO-1,2,3,4-TETRAHYDROQUINOXALINE, 97

cis-3-Amino-1-(trifluoromethyl)cyclobutanol hydrochloride (1:1)

Benzene, 4-butyl-1-isocyanato-2-methyl-

推荐供应商