![1-Oxa-8-azaspiro[4.5]decan-3-ol structure](https://cnstatic.chemtradehub.com/structs/757/757239-76-2-a0ec.webp "1-Oxa-8-azaspiro[4.5]decan-3-ol structure")
100% hyperbranched polymers via the acid-catalyzed Friedel–Crafts aromatic substitution reaction
文献信息
发布日期
2016-07-29
DOI
10.1039/C6PY01168C
影响因子
5.582
作者
Dong Yang, Jie Kong
查看原文
摘要
A highly efficient and benign strategy to synthesize hyperbranched polymers with a degree of branching of 100% was presented via a Friedel–Crafts aromatic substitution reaction of an AB2 monomer, 5-(4-phenoxyphenoxy)isobenzofuran-1,3-dione, in the presence of trifluoromethanesulfonic acid. The molecular weight (Mw: 66.1–294.8 kDa) and the polydispersity (close to 2.0) can be tuned by controlling polymerization conditions. It makes it convenient to tailor hyperbranched polymers for potential application in functional materials.
期刊推荐
Journal of the Indian Institute of Science
Atomization and Sprays
Heteroatom Chemistry
Bioorganic & Medicinal Chemistry Letters
Polycyclic Aromatic Compounds
Bioorganic & Medicinal Chemistry
Critical Reviews in Solid State and Materials Sciences
Herald of the Russian Academy of Sciences
NDT & E International
Acta Metallurgica Sinica-English Letters
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来源期刊
Polymer Chemistry
CiteScore:
8.6
自引率:
7.3%
年发文量:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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