A degradable cross-linked polymer containing dynamic covalent selenide bond

文献信息

发布日期 2017-06-01

DOI 10.1039/C7PY00719A

影响因子 5.582

作者

Weihong Lu, Xiangqiang Pan, Zhengbiao Zhang, Jian Zhu, Nianchen Zhou, Xiulin Zhu

查看原文

摘要

A new method for preparing a degradable cross-linked polymer containing dynamic selenide was demonstrated. 1,2-Bis(2,3,5,6-tetrafluoro-4-vinylphenyl)diselane (FVPDSe) was synthesized and used as a photoinitiator, mediator and dynamic covalent cross-linker to prepare cross-linked polymers via reversible-deactivation radical polymerization with vinyl monomers such as styrene, methyl acrylate, n-butyl acrylate, 2-hydroxyethyl acrylate and methyl methacrylate. After oxidation by hydrogen peroxide, the structure of the cross-linked polymer obtained from the copolymerization of FVPDSe with styrene was carefully analyzed using 1H, 13C, 19F, and 77Se NMR and SEC. In addition, the “livingness” of the obtained cross-linked polymers was also investigated.

期刊推荐

Applied Clay Science

Synthetic Communications

Crystal Research and Technology

Bioorganic Chemistry

Tetrahedron Letters

European Journal of Medicinal Chemistry

Applied Surface Science

Dyes and Pigments

Studies in Conservation

Pharmaceutical Chemistry Journal

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

A degradable cross-linked polymer containing dynamic covalent selenide bond

文献信息

期刊推荐

相关文献

A simple route to deuterated polystyrene block copolymers by reverse iodine transfer polymerisation

Pyrrolo[3,4-g]quinoxaline-6,8-dione-based conjugated copolymers for bulk heterojunction solar cells with high photovoltages

Enhancing the photovoltaic properties of low bandgap terpolymers based on benzodithiophene and phenanthrophenazine by introducing different second acceptor units

A dual stimuli responsive fluorescent probe carrier from a double hydrophilic block copolymer capped with β-cyclodextrin

Synthesis of non-fouling poly[N-(2-hydroxypropyl)methacrylamide] brushes by photoinduced SET-LRP

Synthesis of all-aliphatic polyamide dendrimers based on a 3,3′-diaminopivalic acid scaffold

A library of heptyl mannose-functionalized copolymers with distinct compositions, microstructures and neighboring non-sugar motifs as potent antiadhesives of type 1 piliated E. coli

Photo-polymerizable, low shrinking modular construction kit with high efficiency based on vinylcyclopropanes

Back cover

Far-red/near-infrared fluorescent conjugated polymer nanoparticles with size-dependent chirality and cell imaging applications

您可能还喜欢

如何储存1,2-环己二酮环乙缩醛(CAS号：4746-96-7)？

Ecopladib(CAS号：381683-92-7)的市场或研究趋势如何？

2,3-Dimethyl-3H-imidazo[4,5-c]pyridine(CAS号：52538-09-7)通常如何合成？

2,3,4,5-tetrahydro-1H-3-苯并氮杂环;盐酸盐(CAS号：17379-01-0)的市场或研究趋势如何？

解草嗪(CAS号：68-90-6)安全吗？

如何储存盐酸甘氨酸丁酯(CAS号：13048-99-2)？

什么是2-Iodo-N,N-dimethylbenzamide(CAS号：54616-46-5)？

如何储存2-氨基-N-环己基乙酰胺(CAS号：16817-90-6)？

5-溴-2-(4H-1,2,4-三唑-4-基)吡啶(CAS号：959240-99-4)的市场或研究趋势如何？

2,4-二溴-6-三氟甲基嘧啶(CAS号：785778-00-9)通常如何合成？

来源期刊

Polymer Chemistry

推荐化合物

cis-3-Amino-1-(trifluoromethyl)cyclobutanol hydrochloride (1:1)

(3R,5R)-1-[(Benzyloxy)carbonyl]-5-methyl-3-piperidinecarboxylic acid

N3-ethylpyridine-3,4-diamine

2,2-dideuterio-2-(3,4,5,6-tetradeuterio-2-pyridyl)acetic acid;hydrochloride

Xylometazoline EP Impurity F

推荐供应商