Studies toward the synthesis of strevertenes A and G: stereoselective construction of C1–C19 segments of the molecules
文献信息
发布日期
2018-08-23
DOI
10.1039/C8OB01754A
影响因子
3.876
作者
Tapan Kumar Kuilya, Subhendu Das, Dhiman Saha, Rajib Kumar Goswami
查看原文
摘要
Stereoselective synthesis of common C1–C19 skeletons of pentane macrolides strevertenes A and G possessing 10 stereogenic centers has been achieved using a flexible and convergent strategy. The salient features of this synthetic study include the Evans aldol reaction for the constructions of C2, C3, C13, and C14 centers, CBS reduction for the generation of a C7 center, Hoveyda–Grubbs cross olefin metathesis for the synthesis of C8–C9 bond, and Wittig olefination for the installation of C16–C19 conjugated olefins.
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来源期刊
Organic & Biomolecular Chemistry
CiteScore:
3.4
自引率:
10.3%
年发文量:
1041
Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.
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