Towards improved comprehensive energetic properties by skeleton modification
文献信息
Skeleton modification is an effective way of tuning and achieving desired properties for energetic compounds. In this work, a series of energetic compounds based on the [1,2,4]triazolo[3,4-f][1,2,4]triazine-8(7H)-one backbone have been designed and synthesized. After the skeleton modification of compound 5, the resulting compound 6, which has the same type of energetic group, exhibits higher density (1.951 g cm−3), and better thermal stability and mechanical sensitivities than those of compound 5. Moreover, its energetic hydrazinium salt 8 has a high detonation property (D = 9003 m s−1; P = 30.9 GPa). This research may provide new insights into the design and synthesis of novel energetic compounds with balanced comprehensive properties.
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来源期刊
New Journal of Chemistry

NJC (New Journal of Chemistry) is a broad-based primary journal encompassing all branches of chemistry and its sub-disciplines. It contains full research articles, communications, perspectives and focus articles. This well-established journal, owned by the Centre National de la Recherche Scientifique (CNRS) of France, has been co-published with the Royal Society of Chemistry since January 1998. NJC is the forum for the publication of high-quality, original and significant work that opens new directions in chemistry or other scientific disciplines. In addition to having a significant chemical component, work published in NJC must demonstrate that it will have an impact on areas of research other than that of the reported work.












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