Microporous organic nanoparticles bearing tri-Zn macrocycles: heterogeneous catalysts for the conversion of biomass-derived furan esters to polymer platforms
文献信息
June Young Jang, Gang Min Lee, Jong Doo Lee, Seung Uk Son
Biomass conversion to polymer platforms is presently a crucial issue that requires efficient catalysts. This work suggests a microporous organic polymer (MOP)-based multimetallic heterogeneous Lewis acid catalyst for the synthesis of biomass-derived polymer platforms. MOP nanoparticles bearing tri-Zn macrocycles (MOPN-TZnM) were prepared by the Sonogashira–Hagihara coupling of a predesigned building block bearing tri-Zn macrocyclic moieties with tetra(4-ethynylphenyl)methane. The MOPN-TZnM showed excellent catalytic performance in the transesterification of biomass-derived dimethyl furan-2,5-dicarboxylate with diols to furan-based diols that can be utilized as polymer platforms of polyurethanes.
期刊推荐

Critical Reviews in Solid State and Materials Sciences

NDT & E International

Atomization and Sprays

Bioorganic & Medicinal Chemistry Letters

Journal of Asian Natural Products Research

Acta Metallurgica Sinica-English Letters

Bioorganic & Medicinal Chemistry

Colloid Journal

Herald of the Russian Academy of Sciences

Heteroatom Chemistry
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Journal of Materials Chemistry A

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment


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