Inhibition of oxygen release and stabilization of the bulk structure of lithium-rich layered oxides by strong Mo–O covalent binding

文献信息

发布日期 2023-12-01
DOI 10.1039/D3TA05649J
影响因子 12.732
作者

Huinan Yu, Zhichen Xue, Zhiyuan Xue, Zhongyuan Luo, Chenxi Ding


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摘要

Lithium-rich layered oxides (LLOs) are highly promising materials for next-generation lithium-ion batteries. However, the irreversible oxygen release during charging and discharging can cause severe interfacial side reactions and unfavorable phase transitions, leading to capacity and voltage drops continuously, which is the root cause of deterioration in the performance of LLOs. In this study, an effective modification strategy of constructing strong covalent Mo–O bonds is proposed to change the local coordination environment of oxygen in LLOs and thus inhibits the release of lattice oxygen during cycling. It improves the migration barrier of transition metal elements, suppresses Mn reduction during the cycling process, prevents the occurrence of phase transition from layered to spinel, and plays a role in stabilizing the crystal structure. Moreover, lattice oxygen fixation prevents the release of O−/O2n− (0 < n < 4) species into the electrolyte that leads to undesirable interfacial reactions, and reduces the generation of a series of unfavorable film-forming organics, such as ROCO2Li and ROLi. In this regard, a stable and highly ion-conductive cathode electrolyte interphase is formed on the surface of LLOs. The electrochemical results indicated that the cycling stability of the modified LLOs was significantly improved.

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来源期刊

Journal of Materials Chemistry A

Journal of Materials Chemistry A
CiteScore: 19.5
自引率: 4.7%
年发文量: 2211

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment

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