Fiber-in-tube RuxCr1−xOy as highly efficient electrocatalysts for pH-universal water oxidation via facile bubble desorption

文献信息

发布日期 2023-10-30
DOI 10.1039/D3TA05897B
影响因子 12.732
作者

Chaewon Song, Dasol Jin, Subin Choi, Youngmi Lee


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摘要

Electrospun RuxCr1−xOy nanomaterials were produced using an electrospinning technique followed by a thermal annealing process under oxidative atmospheric conditions. The morphology of the materials was controlled by adjusting the atmospheric O2 concentration during calcination, resulting in various shapes, including core–shell structures and nanofibers. The electrocatalytic activity of RuxCr1−xOy nanomaterials for the oxygen evolution reaction (OER) was assessed with voltammetry under various pH conditions. Specifically, RuxCr1−xOy_20 nanofibers (synthesized in a calcination environment composed of 20% oxygen and 80% helium gases), featuring a fiber-in-tube structure, exhibited the lowest potentials (V vs. RHE) at 10 mA cm−2, reaching 1.47 V under alkaline, 1.49 V under neutral, and 1.44 V under acidic conditions. Furthermore, these nanomaterials displayed the smallest Tafel slopes of 37.5 mV dec−1 in alkaline, 68.9 mV dec−1 in neutral, and 40.8 mV dec−1 in acidic environments. These results clearly indicate the superior OER activity of RuxCr1−xOy_20 in comparison to that of commercial Ir (Ir/C), pure RuOx (Ru/RuO2), and Ru-based electrocatalysts reported in the literature. Additionally, it displayed remarkable stability over 20 h continuous chronopotentiometry tests across all pH ranges and facilitated the desorption of oxygen bubbles generated during the OER process, leading to improved OER activity. The unique core–shell structure of RuxCr1−xOy_20, which dilutes expensive Ru with cheap Cr, presents excellent feasibility as a practical and cost-effective OER catalyst, especially considering the scarcity of pH-universal OER catalysts reported.

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来源期刊

Journal of Materials Chemistry A

Journal of Materials Chemistry A
CiteScore: 19.5
自引率: 4.7%
年发文量: 2211

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment

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